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Oxidation
States of Mercury
Mercury
occurs in three oxidation states:
- Elemental Mercury or Hg0
- Monovalent Mercury or Hg+ or Hg1
- Divalent
Mercury or Hg++ or Hg2+
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Mercury
binds in two states Hg+ (mercurous) and Hg++ (mercuric) to
form mercury compounds that can be either organic or inorganic
mercury compounds.
The
distinction between
Elemental
Mercury, Inorganic
Mercury and Organic
Mercury is
much more important than the oxidation states in determining
toxicity. Organic
mercury compounds are most toxic.
Examples:
- Elemental
Mercury
- A
form of inorganic mercury
- Volatile at room temperature
- Inorganic
Mercury (Mercury Salts)
- Formed
when mercury combines with elements other than carbon,
such as chlorine, sulfur, or oxygen
- Mercuric
chloride, mercuric sulfide, mercurous chloride
- Organic
Mercury
- Formed
when mercury combines with carbon
- Volatile at room temperature
- Methylmercury,
mercuric acetate, methylmercuric chloride, dimethyl
mercury, and phenylmercuric acetate
The routes
of entry into the body associated with mercury are:
- Inhalation
(breathing)
- Absorption
(touching with bare skin)
- Ingestion
Elemental
Mercury emits vapor readily at room temperature.
Elemental
Mercury vapor is colorless, odorless & tasteless.
Elemental
Mercury is highly toxic, especially to children, a
developing fetus, and the elderly.
When mercury is spilled, microscopic "beads" may
be
left behind after cleaning and each "bead" will
continue
to emit vapor.
There are suitable alternatives to mercury and
mercury containing devices for virtually everything
that contains mercury.
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Spilled Mercury on Floor
When mercury spills onto floors and other surfaces,
it fractures into hundreds, even thousands of tiny beads;
many are invisible to the naked eye, yet still emitting
vapor.
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Why remove mercury or screen to ensure that no mercury
contamination exists?
"Mercury
may be the 21st-century lead poisoning," Family Circle Magazine, March 12, 2002, Special
Report: The Hidden Danger in Your
Home, Are You at
Risk for Mercury Poisoning?
"It is important for the general public to understand that either short-term
or long-term exposures to metallic mercury can lead to serious health problems," 1997
National Alert, The Agency for Toxic Substances and
Disease Registry (ATSDR), part of the U.S. Public Health
Service.
"Exposure to high levels of metallic, inorganic or organic mercury can permanently
damage the brain, kidneys, and developing fetus. Effects on
brain functioning may result in irritability, shyness, tremors, changes in vision
or hearing, and
memory problems," April 1999, ToxFAQs for Mercury Fact
Sheet, The Agency for Toxic Substances and Disease Registry (ATSDR),
part of the U.S. Public
Health Service.
"Mercury that is spilled or spread through a school creates an immediate
health issue, and may require expensive cleanup and monitoring," June 2001,
Ohio EPA, Office of Pollution Prevention, Mercury
Awareness for School Teachers
Fact Sheet.
"Prevention is the key to avoiding poisoning in homes, schools and families," 1997
National Alert, The Agency for Toxic Substances and
Disease Registry (ATSDR), part of the U.S. Public Health
Service.
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